Thursday, January 23, 2020

Future Battle? - Seabed Mining

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24-1-9 Deep Sea Mining: do we really need it? - Our Metallic Earth > .
Mining the deep sea: the true cost to the planet | Economist > .Lanthanides - REEs - Omnia per Scientiam >> .
Energy Challenges - Omnia per Scientiam >> .

To meet the world's growing demand for batteries, private companies have turned their attention to mining the ocean floor. But this practice could come at a greater cost to the planet than it's worth.

Terrestrial mining doesn’t have a perfect record, it comes with a long list of environmental and human rights abuses, including pollution and child labor. All this to dig up raw materials like nickel, manganese, and cobalt that are necessary for our lithium-ion batteries.

Some strategies for a carbon-free future depend on making these batteries in much larger numbers and using them as a power source for electric cars or a storage method for electricity generated by renewables. 

But another source of these materials could lie at the bottom of the ocean. Potato-sized lumps called polymetallic nodules are rich in manganese, copper, cobalt, nickel, and other precious metals; and they are found in abundance in some areas like the Clarion-Clipperton Zone that stretches from Hawaii to Mexico.

History’s Largest Mining Operation Is About to Begin
https://www.theatlantic.com/magazine/... .
"Regulations for ocean mining have never been formally established. The United Nations has given that task to an obscure organization known as the International Seabed Authority, which is housed in a pair of drab gray office buildings at the edge of Kingston Harbour, in Jamaica. Unlike most UN bodies, the ISA receives little oversight."

Treasure and Turmoil in the Deep Sea
https://www.nytimes.com/2020/08/14/op... .
"As a result of the mining, animals already living near their physiological limits would be eating mouthfuls of poisonous dirt for breakfast, respiring through clogged gills and squinting through a muddy haze to communicate."

Seabed mining is coming — bringing mineral riches and fears of epic extinctions
https://www.nature.com/articles/d4158... .
"The sea floor there boasts one of the world’s largest untapped collections of rare-earth elements. Some 4,000 metres below the ocean surface, the abyssal ooze of the CCZ holds trillions of polymetallic nodules — potato-sized deposits loaded with copper, nickel, manganese and other precious ores."

21-7-1 First seabed mines may be step closer to reality

The tiny Pacific nation of Nauru has created shockwaves by demanding that the rules for deep sea mining are agreed in the next two years. Environmental groups warn that [regulations concerning seabed mining] will lead to a destructive rush on the mineral-rich seabed "nodules" that are sought by the mining companies. But United Nations officials overseeing deep sea mining say no venture underwater can start for years.

[Partnered with DeepGreen], Nauru, an island state in the Pacific Ocean, has called on the International Seabed Authority - a UN body that oversees the ocean floor - to speed up the regulations that will govern deep sea mining. Nauru has activated a seemingly obscure sub-clause in the UN Convention on the Law of the Sea that allows countries to pull a 'two-year trigger' if they feel negotiations are going too slowly. Nauru, which is partnered with a mining company, DeepGreen, argues that it has "a duty to the international community" to make this move to help achieve "regulatory certainty". It says that it stands to lose most from climate change so it wants to encourage access to the small rocks known as nodules that lie on the sea bed.

[The nodules] are rich in cobalt and other valuable metals that could be useful for batteries and renewable energy systems in the transition away from fossil fuels. The nodules, a habitat for countless forms of life, are estimated to have formed over several million years so any recovery from mining will be incredibly slow. Scientists say they're far from gaining a complete understanding of the ecosystems in the abyssal plains - but already know they're far more vibrant and complex than previously thought.

Still unknown are the impacts of giant machines' stirring up plumes of sediment that are likely to drift over vast distances underwater. Researching this question is a difficult and slow task - and is unlikely to be fully answered within the two-year period initiated by Nauru.

DSM - Deep Sea Mining ↠
Future Battle? - Seabed Mining ..

Wednesday, January 22, 2020

Global Transportation System - US Military

22-10-5 US Military’s Massive Global Transportation System - Wendover > .
24-9-21 How drones change America's future war in the Pacific - Kamome > .
24-5-25 Can Ruscia "Slaughter Us" as Royce Lopez Claims - Ryan McBeth > .  

Friday, January 17, 2020

Lithium - Essential Greener Resource

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Lithium – new environmentally-destructive gold rush in the Andes | DW > .
Lanthanides - REEs - Omnia per Scientiam >> .

Sichuan-Tibet Railway & Tibetan Minerals 

Demand for lithium is expected to outpace global supply as consumers switch to battery-powered vehicles. With China currently leading in processing of the vital raw material, the U.S. government is looking to boost domestic production.

Climate change: Will UK mining drive a green revolution?: The rapid growth of renewable energy and electric vehicles means the demand for the minerals they rely on is set to soar. By 2030, the world could need half as much tin again, and for lithium the increase is a massive 500% by 2050 according to the World Bank. With battery production set to start in the UK, could the answer to their supply lie in the rocks of Cornwall? The abandoned tin mine may open again. With the growth of renewable energy and electric vehicles, demand for some minerals is soaring because next-generation solar panels use tin perovskite.

Lithium was discovered in Cornwall about 150 years ago. Lithium is the main component of the batteries that electric cars use. And with the UK's ban on the sale of new diesel and petrol cars that comes into force in 2030, we will need more and more of it. Currently, lithium is either mined directly from rocks in Australia or taken from salt lakes in South America.

Cornish Lithium thinks it could eventually supply about a third of the UK's future lithium needs. A small borehole has been drilled about a kilometre beneath the ground to access geothermal waters circulating naturally within fractures in the rock. The lithium from the rocks seeps into this underground water, and the brine is pumped back up to the surface.

The company is testing different technologies to extract the metal. The idea is to draw out the lithium and then, once it’s removed, inject the water back underground so the process can be repeated. The energy used to power this process will be from a renewable source - the natural heat from the deep rocks can be converted into electricity, making the process carbon-neutral.

Thursday, January 16, 2020

Metals - Supply

Ga, Ge 
23-7-9 Xina's Gallium & Germanium Export Controls - Asianometry > .
Li
Mining & Refining - Resource Blackmail 
REE 
U

The Earth’s crust is abundant in minerals and ores. Some ores have proven to be a valuable resource for humanity. Iron, for example, derived from iron ore (Hematite), laid the groundwork for the industrial revolution. Aluminum, on the other hand, was a critical strategic resource for aviation during World War I and World War II.
 
China is the world’s largest consumer of iron ore, and despite being the third largest producer, it still imports around 80% of the iron ore it uses each year. The biggest producers of iron ore are Australia, Brazil and China, which collectively account for around two-thirds of global output, with India, Russia, Ukraine and Canada also significant producers, according to the U.S. Geological Survey Mineral Commodity Summaries 2022. China imported a total of 1.12 billion tons of iron ore in 2021, down slightly from 1.17 billion tons in 2020, according to government data. The drop in demand was largely driven by lower steel production in China, as the government placed constraints on the industry in a bid to reduce carbon emissions.

Methane Ice - Seabed Extraction

2021 Fire Ice - Seabed Extraction - Japan's Bid for Energy Independence - VisPol > .

⧫ Energy, Fuel ..
⧫ Essential Resources ..


Methane clathrate (CH4·5.75H2O) or (4CH4·23H2O), also called methane hydrate, hydromethane, methane ice, fire ice, natural gas hydrate, or gas hydrate, is a solid clathrate compound (more specifically, a clathrate hydrate) in which a large amount of methane is trapped within a crystal structure of water, forming a solid similar to ice. A clathrate is a chemical substance consisting of a lattice that traps or contains molecules. The word clathrate is derived from the Latin clathratus (clatratus), meaning ‘with bars, latticed’. Traditionally, clathrate compounds are polymeric and completely envelop the guest molecule, but in modern usage clathrates also include host–guest complexes and inclusion compounds. According to IUPAC, clathrates are inclusion compounds "in which the guest molecule is in a cage formed by the host molecule or by a lattice of host molecules."

Originally thought to occur only in the outer regions of the Solar System, where temperatures are low and water ice is common, significant deposits of methane clathrate have been found under sediments on the ocean floors of the Earth. Methane hydrate is formed when hydrogen-bonded water and methane gas come into contact at high pressures and low temperatures in oceans.

Methane clathrates are common constituents of the shallow marine geosphere and they occur in deep sedimentary structures and form outcrops on the ocean floor. Methane hydrates are believed to form by the precipitation or crystallisation of methane migrating from deep along geological faults. Precipitation occurs when the methane comes in contact with water within the sea bed subject to temperature and pressure. In 2008, research on Antarctic Vostok Station and EPICA Dome C ice cores revealed that methane clathrates were also present in deep Antarctic ice cores and record a history of atmospheric methane concentrations, dating to 800,000 years ago. The ice-core methane clathrate record is a primary source of data for global warming research, along with oxygen and carbon dioxide.

Methane clathrates in continental rocks are trapped in beds of sandstone or siltstone at depths of less than 800 m. Sampling indicates they are formed from a mix of thermally and microbially derived gas from which the heavier hydrocarbons were later selectively removed. These occur in Alaska, Siberia, and Northern Canada.

In 2008, Canadian and Japanese researchers extracted a constant stream of natural gas from a test project at the Mallik gas hydrate site in the Mackenzie River delta. This was the second such drilling at Mallik: the first took place in 2002 and used heat to release methane. In the 2008 experiment, researchers were able to extract gas by lowering the pressure, without heating, requiring significantly less energy. The Mallik gas hydrate field was first discovered by Imperial Oil in 1971–1972.

Experts caution that environmental impacts are still being investigated and that methane—a greenhouse gas with around 25 times as much global warming potential over a 100-year period (GWP100) as carbon dioxide—could potentially escape into the atmosphere if something goes wrong. Furthermore, while cleaner than coal, burning natural gas also creates carbon emissions.

When drilling in oil- and gas-bearing formations submerged in deep water, the reservoir gas may flow into the well bore and form gas hydrates owing to the low temperatures and high pressures found during deep water drilling. The gas hydrates may then flow upward with drilling mud or other discharged fluids. When the hydrates rise, the pressure in the annulus decreases and the hydrates dissociate into gas and water. The rapid gas expansion ejects fluid from the well, reducing the pressure further, which leads to more hydrate dissociation and further fluid ejection. The resulting violent expulsion of fluid from the annulus is one potential cause or contributor to the "kick". (Kicks, which can cause blowouts, typically do not involve hydrates: see Blowout: formation kick).

Measures which reduce the risk of hydrate formation include:
  • High flow-rates, which limit the time for hydrate formation in a volume of fluid, thereby reducing the kick potential.
  • Careful measuring of line flow to detect incipient hydrate plugging.
  • Additional care in measuring when gas production rates are low and the possibility of hydrate formation is higher than at relatively high gas flow rates.
  • Monitoring of well casing after it is "shut in" (isolated) may indicate hydrate formation. Following "shut in", the pressure rises while gas diffuses through the reservoir to the bore hole; the rate of pressure rise exhibit a reduced rate of increase while hydrates are forming.
  • Additions of energy (e.g., the energy released by setting cement used in well completion) can raise the temperature and convert hydrates to gas, producing a "kick".

sī vīs pācem, parā bellum

igitur quī dēsīderat pācem praeparet bellum    therefore, he who desires peace, let him prepare for war sī vīs pācem, parā bellum if you wan...